Product ID:ALODINE 1201
MSDS Date:03/30/1989
FSC:8030
NIIN:00-823-8039
MSDS Number: BPVDD

HENKEL CORPORATION

32100 STEPHENSON HIGHWAY
MADISON HEIGHTS, MI 48071
US

Emergency Phone: 517-263-9430

Info Phone: 583-9300

Cage: DO342

HENKEL CORPORATION-EMERY GROUP

CINCINNATI, OH 45232 US

Telephone: 513-482-2297

Cage: DO342

CHROMIC ACID (SARA 313) CORROSIVE

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: APPROX1%

OSHA PEL 0.05 MG/M3;0.1 MG/M3

ACGIH TLV: 0.05 MG/M3;0.1 MG/M3

POTASSIUM FERRICYANIDE (SARA 313)

CAS: 13746-66-2

Fraction By Weight: <1%

HYDROGEN FLUORIDE (SARA 313) CORROSIVE

CAS: 7664-39-3

RTECS: MW7875000

Fraction By Weight: <1%

OSHA PEL F,2.3MG/M3;2.5MG/M3

ACGIH TLV: F,2.3MG/M3;2.5MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:CHRONIC: CONTAINS FLUORIDE. EXPOSURE
TO FLOURIDES OVER YEARS MAY CAUSE FLUOROSIS. PROLONGED/REPEATED
SKIN CONTACT: "CHROME SORES". LONG TERM EXPOSURE: LIVER/KIDNEY
DAMAGE/DERMATITIS. PROLONGED/REPEATE D INHALATION:
ULCERATION/PERFORMATION OF NASAL SEPTUM.
Explanation of Carcinogenicity:LAB EVIDENCE-AQUEOUS SODIUM DICHROMATE
ADMINISTERED DIRECTLY IN LUNG, AT HIGHEST TOLERATED DOSE, OVER
LIFETIME OF RATS *
Effects of Overexposure:EYES: BURNS/DAMAGE. SKIN: SEVERE BURNS. CHROMIC
ACID-ABSORBED THROUGH SKIN/DAMAGED SKIN. FATAL KIDNEY DAMAGE WAS
REPORTED IN A PERSON WHO EVIDENTLY ABSORBED CHROMIUM TRIOXIDE INTO
BODY. INGEST: GASTRO INTESTINAL DAMAGE/BURNS OF DIGESTIVE TRACT.
INHALE: INJURY/BURNS TO DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:N/K *CAUSES SIGNIFICANTLY INCREASED
INCIDENCE OF LUNG CANCER. EXPECTED; CHROMIC ACID TESTED IN SAME
MANNER, GIVE SIMILAR RESPONSE. SUFFICIENT EVIDENCE FOR
CARCINOGENICITY IN HUMANS/LAB ANIMALS.

First Aid:EYE: IMMED FLUSH W/WATER 15 MIN HOLD LIDS OPEN. GET MED AID.
SKIN: IMMED FLUSH W/WATER 15 MIN-REMOVING CONTAMINATED CLOTHES.
SOAK FOR 1 HR IN ICED SOLUTION (0.13%) ZEPHRIN CHLORIDE (30 CC OF
17% CONCE NTRATE PER GALLON ICED DISTILLED WATER). GET MED AID.
INGEST: DRINK LARGE AMOUNTS WATER. CORROSIVE. DONT INDUCE VOMIT. IF
VOMIT OCCURS, DRINK MORE WATER. GET MED AID. NEVER GIVE ANYTHING BY
MOUTH TO**

Flash Point:NONE
Extinguishing Media:AS REQUIRED TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:CLOTH CONTAMED W/CHEMICAL FLAM. IMMED
REMOVE/RINCE W/WATER. CONTACT W/COMBUST MAT'L CAUSE FIRE. NO
HAZARD-LIQUID FORM/CONTAINS OXIDERS-SUPPLY OXYGEN WHEN DRY.

Spill Release Procedures:WEAR PROTECTIVE CLOTHING. DIKE TO CONTAIN
SPILL. ABSORB ON NON-COMBUSTIBLE MATERIAL (VERMICULITE, SAND,
EARTH) AND STORE IN SUITABLE DRUM. FLUSH THE CONTAMINATED AREA WITH
WATER.

Handling and Storage Precautions:DO NOT GET IN EYES/ON SKIN/ON
CLOTHING. CONTACT W/COMBUSTIBLE MATERIAL MAY CAUSE FIRE. FOR
INDUSTRIAL USE ONLY.
Other Precautions:**AN UNCONSCIOUS PERSON. INHALE: REMOVE TO FRESH
AIR/REMOVE CONTAMINATED CLOTHING. IF BREATHING DIFFICULT,
ADMINISTER OXYGEN. IF RESPIRATION STOPS, GIVE MOUTH TO MOUTH
RESUSCITATION. GET MED AID.

Respiratory Protection:PROVIDE MIST PROTECTION WHERE APPLICABLE. USE
NIOSH OR MSHA APPROVED RESPIRATORS.
Ventilation:LOCAL EXHAUST
Protective Gloves:NEOPRENE/POLYVINYL GLOVES
Eye Protection:CHEMICAL GOGGLES/FACE SHIELD
Other Protective Equipment:EYE WASH FACILITY AND EMERGENCY SHOWER
SHOULD BE IN CLOSE PROXIMITY. APPROPRIATE PROTECTIVE CLOTHING.
Work Hygienic Practices:IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND
RINCE THOROUGHLY W/WATER. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Spec Gravity:1-1.02
pH:<2
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQUID
Corrosion Rate:INGREDS

Stability Indicator/Materials to Avoid:YES
KEEP SEPARATE FROM ALKALIES. ORGANIC MATERIALS, PAINT THINNERS OR
REDUCING AGENTS.
Hazardous Decomposition Products:HYDROGEN CYANIDE

Waste Disposal Methods:CONTACT LICENSED DISPOSAL AGENT. DISPOSE IN
COMPLIANCE W/ALL APPLICABLE LOCAL/STATE/FEDERAL REGS. THIS CHEMICAL
CONTAINS CHROMIUM COMPOUNDS AND FLOURIDE COMPOUNDS. WASTE TREATMENT
AND NEUTRALIZATION M AY BE REQUIRED PRIOR TO DISCHARGE TO SEWER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.